DC Field | Value | Language |
---|---|---|
dc.contributor.author | PARK, J | ko |
dc.contributor.author | KANG, WK | ko |
dc.contributor.author | Ryoo, Ryong | ko |
dc.contributor.author | JUNG, KH | ko |
dc.contributor.author | JANG, DJ | ko |
dc.date.accessioned | 2010-02-22T06:42:36Z | - |
dc.date.available | 2010-02-22T06:42:36Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1994-05 | - |
dc.identifier.citation | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v.80, no.1-3, pp.333 - 339 | - |
dc.identifier.issn | 1010-6030 | - |
dc.identifier.uri | http://hdl.handle.net/10203/16745 | - |
dc.description.abstract | The photophysical behaviours of anthracene in zeolite Y were investigated using various steady state spectroscopic methods and a picosecond time-resolved fluorescence spectroscopic technique. A Xe-129 nuclear magnetic resonance (NMR) study shows that anthracene molecules can be optimally intercalated into the supercages of Na+- and Cu2+-exchanged zeolite Y at 570 and 520 K respectively. Anthracene introduced into the supercage of Na+- exchanged zeolite Y shows excimeric fluorescence with a lifetime of several nanoseconds, as well as monomeric fluorescence with a lifetime of 300 ps. The excimer forms immediately on absorption of a photon. Cu2+-exchanged zeolite Y with anthracene intercalation shows electron spin resonance (ESR) signals and absorption bands attributable to the stable, ground state anthracene cation radical, the Cu+ ion and the trapped electron in the copper ion cluster, indicating charge transfer from anthracene to the Cu2+ ion or copper ion cluster. The excitation energy of anthracene is quenched rapidly by the presence of copper ion. | - |
dc.description.sponsorship | This work was financially supported by Seoul National University Posco Research Fund. We thank the Centre for Molecular Science and the Korea Research Institute of Standards and Science for use of their equipment. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | ELSEVIER SCIENCE SA LAUSANNE | - |
dc.subject | AROMATIC-HYDROCARBONS | - |
dc.subject | FLUORESCENCE-SPECTRA | - |
dc.subject | ELECTRON-TRANSFER | - |
dc.subject | EXCIMER FORMATION | - |
dc.subject | METAL-IONS | - |
dc.subject | Y-ZEOLITE | - |
dc.subject | PYRENE | - |
dc.subject | STATE | - |
dc.subject | MOLECULES | - |
dc.subject | NMR | - |
dc.title | A STUDY ON THE PHOTOPHYSICAL PROPERTIES OF ANTHRACENE IN ZEOLITE | - |
dc.type | Article | - |
dc.identifier.wosid | A1994NR31100043 | - |
dc.identifier.scopusid | 2-s2.0-0000904012 | - |
dc.type.rims | ART | - |
dc.citation.volume | 80 | - |
dc.citation.issue | 1-3 | - |
dc.citation.beginningpage | 333 | - |
dc.citation.endingpage | 339 | - |
dc.citation.publicationname | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | - |
dc.identifier.doi | 10.1016/1010-6030(93)01007-O | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Ryoo, Ryong | - |
dc.contributor.nonIdAuthor | PARK, J | - |
dc.contributor.nonIdAuthor | KANG, WK | - |
dc.contributor.nonIdAuthor | JUNG, KH | - |
dc.contributor.nonIdAuthor | JANG, DJ | - |
dc.type.journalArticle | Article; Proceedings Paper | - |
dc.subject.keywordPlus | AROMATIC-HYDROCARBONS | - |
dc.subject.keywordPlus | FLUORESCENCE-SPECTRA | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | EXCIMER FORMATION | - |
dc.subject.keywordPlus | METAL-IONS | - |
dc.subject.keywordPlus | Y-ZEOLITE | - |
dc.subject.keywordPlus | PYRENE | - |
dc.subject.keywordPlus | STATE | - |
dc.subject.keywordPlus | MOLECULES | - |
dc.subject.keywordPlus | NMR | - |
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