Calculated chemical equations using thermodynamics suggest that elemental Te-0 is easily induced during bromine-based etching process on the HgCdTe surface and the induced elemental Te-0 can be removed by chemical reaction with hydrazine, forming volatile H2Te. X-ray photoelectron spectroscopy (XPS) confirmed these chemical reactions. The induced elemental Te-0 is believed to play a role as surface generation-recombination centers in CdTe/HgCdTe interface, which was confirmed by XPS, ideality factor, and energy-dispersive interface trap density (D-it) analyses.