Particle and breath figure formation of triblock copolymers having self-complementary hydrogen-bonding units

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Novel triblock copolymers having self-complementary hydrogen-bonding units were synthesized by using reversible additionfragmentation transfer polymerization. As characterized by dynamic light scattering and atomic force microscopy, these polymers formed noncovalently crosslinked polymer particles and showed an aggregation behavior by intermolecular and intramolecular interactions. At low concentration, polymers formed nanoparticles, and the particle diameter increased with increasing polymer concentration. Well-ordered hexagonal microstructures were prepared by Breath Figure technique with the triblock copolymers.(c) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
Publisher
WILEY-BLACKWELL
Issue Date
2012-11
Language
English
Article Type
Article
Citation

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.50, no.21, pp.4408 - 4414

ISSN
0887-624X
DOI
10.1002/pola.26256
URI
http://hdl.handle.net/10203/104517
Appears in Collection
NT-Journal Papers(저널논문)CH-Journal Papers(저널논문)
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