DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Sun Dal | ko |
dc.contributor.author | Ka, Duyoun | ko |
dc.contributor.author | Chung, Im Sik | ko |
dc.contributor.author | Kim, Sang Youl | ko |
dc.date.accessioned | 2013-03-12T07:22:00Z | - |
dc.date.available | 2013-03-12T07:22:00Z | - |
dc.date.created | 2012-06-11 | - |
dc.date.created | 2012-06-11 | - |
dc.date.issued | 2012-04 | - |
dc.identifier.citation | MACROMOLECULES, v.45, no.7, pp.3023 - 3031 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | http://hdl.handle.net/10203/101654 | - |
dc.description.abstract | High-molecular-weight poly(biphenylene oxide)s (PBPO) were prepared from AB-type monomers, 4'(3')-hydroxy-4-nitro-2,6-bis(trifluoromethyl)biphenyl, through a meta-activated nitro displacement reaction. The displacement of nitro leaving group activated by the two trifluoromethylgroups at the meta-position produced high-molecular-weight polymers, which implies that nucleophilic aromatic substitution reaction of the nitro leaving group proceeded very effectively with two activating groups at the meta-position. The obtained polymers have weight-average molecular weight of 20 800-143 300 g/mol and molecular weight distribution of 1.68-2.85. While two homopolymers of 4'- or 3'-hydroxy-4-nitro-2,6-bis(trifluoromethyl)biphenyl, p-PBPO and m-PBPO, showed a semicrystalline morphology, copolymers of the two monomers were amorphous and dissolved in a wide range of organic solvents. The PBPOs possessed a high glass transition temperature (T-g) in the range of 169 to 208 degrees C depending on their structure and high thermal stability with 10% weight loss temperatures from 486 to 542 degrees C in nitrogen and from 465 to 516 degrees C in air. Moreover, PBPOs containing two trifluoromethyl groups showed low refractive indices in the range of 1.4979-1.5052 as well as low birefringence values of 0.0095-0.0148. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | AROMATIC-SUBSTITUTION REACTION | - |
dc.subject | LOW DIELECTRIC-CONSTANT | - |
dc.subject | SOLUBLE POLYIMIDES | - |
dc.subject | UNSYMMETRICAL DIAMINE | - |
dc.subject | PHYSICAL-PROPERTIES | - |
dc.subject | PENDENT GROUP | - |
dc.subject | MONOMER | - |
dc.subject | POLYMERIZATION | - |
dc.subject | SULFONE)S | - |
dc.subject | POLYMERS | - |
dc.title | Poly(arylene ether)s with Low Refractive Indices: Poly(biphenylene oxide)s with Trifluoromethyl Pendant Groups via a Meta-Activated Nitro Displacement Reaction | - |
dc.type | Article | - |
dc.identifier.wosid | 000302511500011 | - |
dc.identifier.scopusid | 2-s2.0-84859613317 | - |
dc.type.rims | ART | - |
dc.citation.volume | 45 | - |
dc.citation.issue | 7 | - |
dc.citation.beginningpage | 3023 | - |
dc.citation.endingpage | 3031 | - |
dc.citation.publicationname | MACROMOLECULES | - |
dc.identifier.doi | 10.1021/ma2028209 | - |
dc.contributor.localauthor | Kim, Sang Youl | - |
dc.contributor.nonIdAuthor | Chung, Im Sik | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | AROMATIC-SUBSTITUTION REACTION | - |
dc.subject.keywordPlus | LOW DIELECTRIC-CONSTANT | - |
dc.subject.keywordPlus | SOLUBLE POLYIMIDES | - |
dc.subject.keywordPlus | UNSYMMETRICAL DIAMINE | - |
dc.subject.keywordPlus | PHYSICAL-PROPERTIES | - |
dc.subject.keywordPlus | PENDENT GROUP | - |
dc.subject.keywordPlus | MONOMER | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | SULFONE)S | - |
dc.subject.keywordPlus | POLYMERS | - |
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