Nuclear motion captured by the slow electron velocity imaging technique in the tunnelling predissociation of the S(1) methylamine

Cited 10 time in webofscience Cited 0 time in scopus
  • Hit : 298
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorAhn, Doo-Sikko
dc.contributor.authorLee, Jeong-Mookko
dc.contributor.authorPark, Young-Choonko
dc.contributor.authorLee, Yoon-Supko
dc.contributor.authorKim, Sang-Kyuko
dc.date.accessioned2013-03-11T03:32:20Z-
dc.date.available2013-03-11T03:32:20Z-
dc.date.created2012-03-07-
dc.date.created2012-03-07-
dc.date.issued2012-01-
dc.identifier.citationJOURNAL OF CHEMICAL PHYSICS, v.136, no.2-
dc.identifier.issn0021-9606-
dc.identifier.urihttp://hdl.handle.net/10203/98154-
dc.description.abstractPredissociation dynamics of methylamines (CH3NH2 and CH3ND2) on the first electronically excited states are studied using the slow-electron velocity imaging method to unravel the multi-dimensional nature of the N-H(D) chemical bond dissociation reaction which occurs via tunnelling. The nearly free internal rotation around the C-N bond axis is found to be strongly coupled to the reaction pathway, revealing nuclear motions actively involved in the tunnelling process on the S-1 potential energy surfaces. The vibrational state-resolved energy and angular distributions of photoelectron, ejected from the ionization mediated by the metastable intermediate S-1 state provide a unique way for mapping the predissociative potential energy surfaces. (C) 2012 American Institute of Physics. [doi:10.1063/1.3675566]-
dc.languageEnglish-
dc.publisherAMER INST PHYSICS-
dc.subjectINTRAMOLECULAR ORBITAL ALIGNMENT-
dc.subjectPHOTOELECTRON-SPECTROSCOPY-
dc.subjectVIBRATIONAL-STRUCTURES-
dc.subject(A)OVER-TILDE STATES-
dc.subjectDYNAMICS-
dc.subjectPHOTODISSOCIATION-
dc.subjectCH3NH2-
dc.subjectCD3I-
dc.subjectCH3I-
dc.titleNuclear motion captured by the slow electron velocity imaging technique in the tunnelling predissociation of the S(1) methylamine-
dc.typeArticle-
dc.identifier.wosid000299126400023-
dc.identifier.scopusid2-s2.0-84855930059-
dc.type.rimsART-
dc.citation.volume136-
dc.citation.issue2-
dc.citation.publicationnameJOURNAL OF CHEMICAL PHYSICS-
dc.identifier.doi10.1063/1.3675566-
dc.contributor.localauthorLee, Yoon-Sup-
dc.contributor.localauthorKim, Sang-Kyu-
dc.type.journalArticleArticle-
dc.subject.keywordPlusINTRAMOLECULAR ORBITAL ALIGNMENT-
dc.subject.keywordPlusPHOTOELECTRON-SPECTROSCOPY-
dc.subject.keywordPlusVIBRATIONAL-STRUCTURES-
dc.subject.keywordPlus(A)OVER-TILDE STATES-
dc.subject.keywordPlusDYNAMICS-
dc.subject.keywordPlusPHOTODISSOCIATION-
dc.subject.keywordPlusCH3NH2-
dc.subject.keywordPlusCD3I-
dc.subject.keywordPlusCH3I-
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 10 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0