DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ahn, Doo-Sik | ko |
dc.contributor.author | Lee, Jeong-Mook | ko |
dc.contributor.author | Park, Young-Choon | ko |
dc.contributor.author | Lee, Yoon-Sup | ko |
dc.contributor.author | Kim, Sang-Kyu | ko |
dc.date.accessioned | 2013-03-11T03:32:20Z | - |
dc.date.available | 2013-03-11T03:32:20Z | - |
dc.date.created | 2012-03-07 | - |
dc.date.created | 2012-03-07 | - |
dc.date.issued | 2012-01 | - |
dc.identifier.citation | JOURNAL OF CHEMICAL PHYSICS, v.136, no.2 | - |
dc.identifier.issn | 0021-9606 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98154 | - |
dc.description.abstract | Predissociation dynamics of methylamines (CH3NH2 and CH3ND2) on the first electronically excited states are studied using the slow-electron velocity imaging method to unravel the multi-dimensional nature of the N-H(D) chemical bond dissociation reaction which occurs via tunnelling. The nearly free internal rotation around the C-N bond axis is found to be strongly coupled to the reaction pathway, revealing nuclear motions actively involved in the tunnelling process on the S-1 potential energy surfaces. The vibrational state-resolved energy and angular distributions of photoelectron, ejected from the ionization mediated by the metastable intermediate S-1 state provide a unique way for mapping the predissociative potential energy surfaces. (C) 2012 American Institute of Physics. [doi:10.1063/1.3675566] | - |
dc.language | English | - |
dc.publisher | AMER INST PHYSICS | - |
dc.subject | INTRAMOLECULAR ORBITAL ALIGNMENT | - |
dc.subject | PHOTOELECTRON-SPECTROSCOPY | - |
dc.subject | VIBRATIONAL-STRUCTURES | - |
dc.subject | (A)OVER-TILDE STATES | - |
dc.subject | DYNAMICS | - |
dc.subject | PHOTODISSOCIATION | - |
dc.subject | CH3NH2 | - |
dc.subject | CD3I | - |
dc.subject | CH3I | - |
dc.title | Nuclear motion captured by the slow electron velocity imaging technique in the tunnelling predissociation of the S(1) methylamine | - |
dc.type | Article | - |
dc.identifier.wosid | 000299126400023 | - |
dc.identifier.scopusid | 2-s2.0-84855930059 | - |
dc.type.rims | ART | - |
dc.citation.volume | 136 | - |
dc.citation.issue | 2 | - |
dc.citation.publicationname | JOURNAL OF CHEMICAL PHYSICS | - |
dc.identifier.doi | 10.1063/1.3675566 | - |
dc.contributor.localauthor | Lee, Yoon-Sup | - |
dc.contributor.localauthor | Kim, Sang-Kyu | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | INTRAMOLECULAR ORBITAL ALIGNMENT | - |
dc.subject.keywordPlus | PHOTOELECTRON-SPECTROSCOPY | - |
dc.subject.keywordPlus | VIBRATIONAL-STRUCTURES | - |
dc.subject.keywordPlus | (A)OVER-TILDE STATES | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordPlus | PHOTODISSOCIATION | - |
dc.subject.keywordPlus | CH3NH2 | - |
dc.subject.keywordPlus | CD3I | - |
dc.subject.keywordPlus | CH3I | - |
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