Angularly Fused Triquinanes from Linear Substrates through Trimethylenemethane Diyl [2+3] Cycloaddition Reaction
Angularly fused triquinanes were synthesized from linear dienes and phenyl(propynyl)iodonium salt through trimethylenemethane (TMM) diyl mediated [2 + 3] cycloaddition reaction. TMM diyl intermediates were obtained from alkylidene carbenes generated from reactions of alkynyliodonium salts with nucleophiles.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2010-06
- Language
- English
- Article Type
- Article
- Keywords
ALKYNYLIODONIUM SALTS; CYCLIZATION; SINGLET
- Citation
ORGANIC LETTERS, v.12, no.11, pp.2672 - 2674
- ISSN
- 1523-7060
- Appears in Collection
- CH-Journal Papers(저널논문)
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