Intermolecular Oxidative C-N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp(2) and Benzylic sp(3) C-H Bond Imidation
A new synthetic approach toward intermolecular oxidative C-N bond formation of arenes has been developed under transition-metal-free conditions. Complete control of chemoselectivity between aryl sp(2) and benzylic sp(3) C-H bond imidation was achieved by the choice of nitrogen sources, representatively being phthalimide and dibenzenesulfonimide, respectively.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2011-10
- Language
- English
- Article Type
- Article
- Keywords
ELECTROPHILIC AROMATIC-SUBSTITUTION; HYPERVALENT IODINE COMPOUNDS; CATALYZED DIRECT AMINATION; NITRENIUM IONS; HETEROCYCLIC-COMPOUNDS; AMBIENT-TEMPERATURE; ACYLNITRENIUM IONS; SINGLE-ELECTRON; AMIDATION; ROUTE
- Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.41, pp.16382 - 16385
- ISSN
- 0002-7863
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
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