Radical Cyanation of Alkyl Iodides with Diethylphosphoryl Cyanide
The beta-elimination of an organophosphoryl group from an iminyl radical is observed for the first time. On the basis of this finding, radical cyanation of alkyl iodides is achieved by using diethylphosphoryl cyanide.
- Publisher
- GEORG THIEME VERLAG KG
- Issue Date
- 2009-01
- Language
- English
- Article Type
- Article
- Keywords
INTRAMOLECULAR ACYLATION APPROACH; CARBON BOND FORMATION; BETA-ELIMINATION; ACYLPHOSPHONATE DERIVATIVES; CYCLIZATION REACTIONS; HYPOPHOSPHOROUS ACID; PHOSPHONATE GROUP; SULFONYL AZIDES; NITROGEN BONDS; TIN
- Citation
SYNLETT, no.1, pp.81 - 84
- ISSN
- 0936-5214
- Appears in Collection
- CH-Journal Papers(저널논문)
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