Dimethyl Sulfoxide/Potassium Hydroxide: A Superbase for the Transition Metal-Free Preparation of Cross-Coupling Products
Potassium hydroxide (KOH) in dimethyl sulfoxide (DMSO) forms a superbasic medium that allows one to access cross-coupling products from reactions between aryl halides with various sulfur-, oxygen- and nitrogen-based nucleophiles under transition metal-free conditions.
- Publisher
- WILEY-V C H VERLAG GMBH
- Issue Date
- 2010-11
- Language
- English
- Article Type
- Article
- Keywords
LIGAND-FREE CONDITIONS; POTASSIUM TERT-BUTOXIDE; CATALYZED C-N; AROMATIC NUCLEOPHILIC-SUBSTITUTION; DIPOLAR APROTIC-SOLVENTS; ARYL HALIDES; BOND FORMATION; BUTYL ALCOHOL; DIARYL ETHERS; COPPER
- Citation
ADVANCED SYNTHESIS CATALYSIS, v.352, no.17, pp.2892 - 2898
- ISSN
- 1615-4150
- Appears in Collection
- CH-Journal Papers(저널논문)
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