DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Jin-Ho | ko |
dc.contributor.author | Chang, Suk-Bok | ko |
dc.date.accessioned | 2013-03-08T15:34:45Z | - |
dc.date.available | 2013-03-08T15:34:45Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2010-08 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.30, pp.10272 - 10274 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/93433 | - |
dc.description.abstract | An unprecedented protocol for cyanation at arene C-H bonds has been developed by employing N,N-dimethylformamide and ammonia as a combined source for the cyano "CN" unit. Isotopic incorporation experiments revealed that the carbon and nitrogen of the "CN" originate from the N,N-dimethyl moiety of DMF and ammonia, respectively. The present cyanation reaction shows an excellent degree of regioselectivity, producing only monosubstituted nitriles at the less hindered C-H position, and it allows for the preparation of doubly labeled nitrile compounds for the first time. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | TRANSITION-METAL | - |
dc.subject | HALIDES | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | EFFICIENT | - |
dc.subject | HALOGEN | - |
dc.subject | AMINES | - |
dc.title | A New Combined Source of "CN" from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C-H Bonds | - |
dc.type | Article | - |
dc.identifier.wosid | 000280456100023 | - |
dc.identifier.scopusid | 2-s2.0-77955035169 | - |
dc.type.rims | ART | - |
dc.citation.volume | 132 | - |
dc.citation.issue | 30 | - |
dc.citation.beginningpage | 10272 | - |
dc.citation.endingpage | 10274 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/ja104917t | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Chang, Suk-Bok | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | TRANSITION-METAL | - |
dc.subject.keywordPlus | HALIDES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | HALOGEN | - |
dc.subject.keywordPlus | AMINES | - |
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