Solvent effect on sulfur ylide mediated epoxidation reaction
The solvent effect on sulfur ylide mediated epoxidation reaction was studied systematically. While higher trans/cis ratio of the epoxide was obtained in the more polar solvent, protic solvent produced the lower trans/cis ratio than any aprotic solvent.
- Publisher
- KOREAN CHEMICAL SOC
- Issue Date
- 2007
- Language
- English
- Article Type
- Article
- Keywords
2-STEP ASYMMETRIC-SYNTHESIS; COREY-CHAYKOVSKY REACTION; IN-SITU GENERATION; SULFONIUM YLIDES; CATALYTIC CYCLE; CHIRAL AUXILIARY; DARZENS REACTION; DIAZO-COMPOUNDS; ALDEHYDES; EPOXIDES
- Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.28, no.11, pp.2051 - 2055
- ISSN
- 0253-2964
- Appears in Collection
- CH-Journal Papers(저널논문)
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