A stereocontrolled synthetic route to the C1-C18 subunit of pamamycin-607
The C1 C18 subunit 2 of the 16-membered macrodiolide pamamycin-607 has been synthesized stereo selectively using the Ag2CO3-mediated intramolecular iodoetherification for the two cis-2,5-disubstituted tetrahydrofurans, crotylation and cuprate epoxide opening for the hydroxyl and methyl substituents. (C) 2002 Elsevier Science Ltd. All rights reserved.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Issue Date
- 2002-05
- Language
- English
- Article Type
- Article
- Keywords
MYCELIUM-INDUCING SUBSTANCE; CHIRAL SULFOXIDE GROUP; STREPTOMYCES-ALBONIGER; ASYMMETRIC-SYNTHESIS; STEREOSELECTIVE SYNTHESIS; NATURAL-PRODUCTS; REAGENT SYSTEM; HYDROXY-GROUP; IODO-GROUP; ANTIBIOTICS
- Citation
TETRAHEDRON LETTERS, v.43, no.20, pp.3613 - 3616
- ISSN
- 0040-4039
- Appears in Collection
- CH-Journal Papers(저널논문)
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