A novel one-dimensional chain complex composed of oxo-centered trinuclear manganese clusters

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A new linear chain complex of oxo-centered trinuclear manganese clusters, [{(Mn2MnO)-Mn-III-O-II(O2CCHCl2)(6)(H2O)}{Mn-(O2CCHCl2)(2)(H2O)(4)}](n) (1), has been synthesized by treatment of a mixture of Mn(OAC)(2).4H(2)O and dichloroacetic acid in dichloromethane with KMnO4, In this complex chains are formed by hydrogen bonding between carboxylate oxygens and coordinated water molecules, forming a two-dimensional structure. Antiferromagnetic coupling was observed by variable-temperature magnetic measurements. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2003-07
Language
English
Article Type
Article
Keywords

R = ME; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; WATER; PH

Citation

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no.14, pp.2563 - 2566

ISSN
1434-1948
DOI
10.1002/ejic.200300212
URI
http://hdl.handle.net/10203/83324
Appears in Collection
CH-Journal Papers(저널논문)
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