A facile synthesis of 1,2-oxaphospholenes and stereoselective conversion into oxaphospholanes

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Treatment of alpha-acylaltylphosphonates with m-CPBA in the presence of MgSO4, afforded 1,2-oxaphosphol-3-enes 2-oxides and the subsequent cuprate addition produced 1,2-oxaphospholanes stereo selectively, (C) 2003 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2003-07
Language
English
Article Type
Article
Keywords

RING-CLOSING METATHESIS; CYCLIC PHOSPHONATE ANALOGS; PROPARGYL ALCOHOLS; ANOMERIC POSITION; ORGANIC-SYNTHESIS; VINYLPHOSPHONATES; STEREOCHEMISTRY; HETEROCYCLES; DERIVATIVES; EPOXIDATION

Citation

TETRAHEDRON LETTERS, v.44, no.31, pp.5811 - 5814

ISSN
0040-4039
DOI
10.1016/S0040-4039(03)01395-9
URI
http://hdl.handle.net/10203/82707
Appears in Collection
CH-Journal Papers(저널논문)
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