Versatile formation of [2]catenane and [2]pseudorotaxane structures; Threading and noncovalent stoppering by a self-assembled macrocycle

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A self-assembled dimeric macrocycle between 4,4'-bis(4-pyridylmethoxy)biphenyl (L) and (en)Pd(NO3)(2) Was constructed, and its interactions with cyclodextrins of different cavity size resulted in the formation of [2]catenane and [2]pseudorotaxane systems, respectively. The structures were identified by 1D and 2D NMR spectroscopy and cold spray ionization mass (CSI-MS) spectrometry.
Publisher
AMER CHEMICAL SOC
Issue Date
2004
Language
English
Article Type
Article
Keywords

CYCLODEXTRIN; COMPLEXES; ROTAXANE; ROTATION; SITES; F-1-ATPASE; MOTORS; KNOTS

Citation

ORGANIC LETTERS, v.6, no.7, pp.1079 - 1082

ISSN
1523-7060
DOI
10.1021/ol036127l
URI
http://hdl.handle.net/10203/78822
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