A highly efficient synthesis of (S)-(+)-N-Boc-coniine using ring-closing olefin metathesis (RCM)

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Optically active (S)-(+)-coniine as an N-Boc protected form was concisely prepared starting from an amino acid, L-norvaline. The key step involved a ring-closing olefin metathesis (RCM) of the dialkenyl compound 6 to give the corresponding cyclic olefin 8 in an essentially quantitative yield. (C) 1999 Elsevier Science Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
1999-07
Language
English
Article Type
Article
Keywords

PIPERIDINE ALKALOIDS; ORGANIC-SYNTHESIS

Citation

TETRAHEDRON LETTERS, v.40, no.30, pp.5581 - 5582

ISSN
0040-4039
DOI
10.1016/S0040-4039(99)01081-3
URI
http://hdl.handle.net/10203/75584
Appears in Collection
CH-Journal Papers(저널논문)
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