Highly stereoselective and efficient hydrosilylation of terminal alkynes catalyzed by [RuCl2(p-cymene)](2)

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With [RuCl2(p-cymene)](2) as a catalyst, extremely high regio- and stereoselectivity was observed in the hydrosilylation reaction of various terminal alkynes under mild conditions to afford beta-(Z)-vinylsilanes in excellent yields. A dramatic directing effect was also observed when alkynes having a hydroxyl group at the beta position to the triple bond were employed as a substrate, and in these cases regioisomeric alpha-vinylsilanes were generated with excellent selectivity.
Publisher
AMER CHEMICAL SOC
Issue Date
2000-06
Language
English
Article Type
Article
Keywords

COMPLEXES; RHODIUM; ISOMERIZATION; SILICON

Citation

ORGANIC LETTERS, v.2, no.13, pp.1887 - 1889

ISSN
1523-7060
DOI
10.1021/ol0059697
URI
http://hdl.handle.net/10203/75507
Appears in Collection
CH-Journal Papers(저널논문)
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