A new synthesis procedure for titanium-containing zeolites under strong alkaline conditions and the catalytic activity for partial oxidation and photocatalytic decomposition

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A new synthesis procedure for titanium-containing aluminosilicate zeolites has been obtained using a clear colloidal dispersion (sol) which was prepared with titanium isopropoxide, water, hydrochloric acid and colloidal silica, Ludox. When NaY, KL, offretite, mordenite and ZSM-5 zeolites were crystallized from the sol following conventional hydrothermal crystallization procedures, all the aluminosilicate zeolites showed the same X-ray absorption fine structure at the Ti K edge indicating framework Ti. The zeolites showed remarkable catalytic activity for the partial oxidation of cyclohexene using H2O2 as an oxidant and the photocatalytic decomposition of trichloroethene using water.
Publisher
BALTZER SCI PUBL BV
Issue Date
1996
Language
English
Article Type
Article
Keywords

CRYSTALLIZATION KINETICS; SILICALITES

Citation

CATALYSIS LETTERS, v.37, no.3-4, pp.217 - 221

ISSN
1011-372X
URI
http://hdl.handle.net/10203/75070
Appears in Collection
CH-Journal Papers(저널논문)
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