Predissociating resonances of Cs-2 - Theory and experiment

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We present the experimental observation and detailed quantum mechanical analysis of the complex resonances occurring through multiple predissociation pathways. The complex features in the photodissociation spectrum of Cs-2 are well reproduced by the close-coupling calculation including three channels. A very narrow resonance with a linewidth of similar to 2 x 10(-7) cm(-1) is predicted. It is shown that q-reversal can occur in predissociation with only two channels involved.
Publisher
VCH PUBLISHERS INC
Issue Date
1997-03
Language
English
Article Type
Article; Proceedings Paper
Keywords

RESOLUTION LASER SPECTROSCOPY; POSITIVE-ENERGY SPECTRUM; COLD MOLECULAR-BEAM; IONIZATION SPECTROSCOPY; THEORETICAL-ANALYSIS; CROSS-SECTIONS; PHOTODISSOCIATION; TRANSITION; PHOTOIONIZATION; STATE

Citation

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.101, no.3, pp.407 - 413

ISSN
0005-9021
URI
http://hdl.handle.net/10203/74270
Appears in Collection
CH-Journal Papers(저널논문)
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