Free Radical-mediated Carboxylation by Radical Reactions of Alkyl Iodides with Methyl Oxalyl Chloride

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Free radical-mediated carboxylation is achieved by treatment of alkyl iodides with methyl oxalyl chloride and bis(tributyltin) in benzene at 350 nm to afford the corresponding acid chlorides as a major product along with a small amount of the methyl esters. (C) 1998 Elsevier Science Ltd. All rights reserved.
Publisher
Pergamon-Elsevier Science Ltd
Issue Date
1998-10
Language
English
Article Type
Article
Keywords

ACYLATION APPROACH; SUBSTITUTION; KINETICS

Citation

TETRAHEDRON LETTERS, v.39, no.40, pp.7317 - 7320

ISSN
0040-4039
URI
http://hdl.handle.net/10203/72528
Appears in Collection
CH-Journal Papers(저널논문)
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