Kinetic Studies of Intramolecular Additions of Alkyl Radicals onto Imines

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The approximate rate constants for 5-exo and 6-exo cyclizations of alkyl radicals onto imines have been kinetically determined to be 6.0x10(6) s(-1) and 6.7x10(5) s(-1) at 80 degrees C, respectively. Alkyl radical additions to imines were essentially irreversible and considerably slower than alkyl radical additions to hydrazones. Copyright (C) 1996 Elsevier Science Ltd
Publisher
Pergamon-Elsevier Science Ltd
Issue Date
1997-01
Language
English
Article Type
Article
Keywords

N-AZIRIDINYL IMINES; OMEGA-FORMYLALKYL RADICALS; NORMAL-BUTYLTIN HYDRIDE; RING EXPANSION; RATE CONSTANTS; OXIME ETHERS; FUSED CYCLOBUTANONES; ORGANIC-SYNTHESIS; CHAIN REACTIONS; CYCLIZATION

Citation

TETRAHEDRON, v.53, no.1, pp.73 - 80

ISSN
0040-4020
URI
http://hdl.handle.net/10203/69201
Appears in Collection
CH-Journal Papers(저널논문)
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