(3)DELTA-(1)SIGMA+ TRANSITION OF RBCS OBSERVED IN A VERY COLD MOLECULAR-BEAM

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A new excitation band of RbCs is observed near 605 nm in a very cold molecular beam using the resonance-enhanced two photon ionization (RE2PI) method. From the rotational contour analysis and comparison with ab initio calcualtions, the new excitation band is assigned to the (1)3DELTA(OMEGA = 1)-X 1SIGMA+ transition. We determine the term value as T(e) = 16481.65 +/- 0.15 cm-1 and the dissociation energy as D(e) = 1862.8 +/- 1.2 cm-1.
Publisher
ELSEVIER SCIENCE BV
Issue Date
1993-09
Language
English
Article Type
Article
Keywords

LASER-INDUCED FLUORESCENCE; 1-SIGMA+ GROUND-STATE; ROTATIONAL ANALYSIS; SPECTROSCOPIC INVESTIGATIONS; CS2

Citation

CHEMICAL PHYSICS LETTERS, v.212, no.3-4, pp.271 - 276

ISSN
0009-2614
DOI
10.1016/0009-2614(93)89325-C
URI
http://hdl.handle.net/10203/65124
Appears in Collection
CH-Journal Papers(저널논문)
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