DC Field | Value | Language |
---|---|---|
dc.contributor.author | Seo, Min Seob | ko |
dc.contributor.author | Jang, Sumin | ko |
dc.contributor.author | Jung, Hoimin | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.date.accessioned | 2019-01-22T08:30:57Z | - |
dc.date.available | 2019-01-22T08:30:57Z | - |
dc.date.created | 2018-12-26 | - |
dc.date.created | 2018-12-26 | - |
dc.date.created | 2018-12-26 | - |
dc.date.issued | 2018-12 | - |
dc.identifier.citation | JOURNAL OF ORGANIC CHEMISTRY, v.83, no.23, pp.14300 - 14306 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10203/249004 | - |
dc.description.abstract | The favorable effect of 2-hydroxyphenyl groups for ketimine formation with benzophenone was demonstrated by combining computational and experimental studies. Although direct imine formation between benzophenone and primary amines is challenging, 2-hydroxybenzophenone or 2,2'-dihydroxybenzophenone was readily used for ketimine formation with various primary alkyl amines and anilines. Measured activation parameters and calculated energy profiles indicated that the 2-hydroxyphenyl group can lower both activation barriers and equilibrium energies by establishing intra-molecular and intermolecular hydrogen-bonding interactions. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Hydrogen-Bonding-Assisted Ketimine Formation of Benzophenone Derivatives | - |
dc.type | Article | - |
dc.identifier.wosid | 000452929900008 | - |
dc.identifier.scopusid | 2-s2.0-85058180352 | - |
dc.type.rims | ART | - |
dc.citation.volume | 83 | - |
dc.citation.issue | 23 | - |
dc.citation.beginningpage | 14300 | - |
dc.citation.endingpage | 14306 | - |
dc.citation.publicationname | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.joc.8b01908 | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.contributor.nonIdAuthor | Jung, Hoimin | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | BASE | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | PHASE | - |
dc.subject.keywordPlus | ION | - |
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