Piers' borane- mediated hydrosilylation of epoxides and cyclic ethers
We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)(2)BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)(2)BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2018-07
- Language
- English
- Article Type
- Article
- Keywords
CATALYTIC HYDROGENOLYSIS; SI-H; REDUCTION; MECHANISM; ALCOHOLS; BORON; POLYMERIZATION; DEOXYGENATION; HYDROBORATION; REARRANGEMENT
- Citation
CHEMICAL COMMUNICATIONS, v.54, no.52, pp.7243 - 7246
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
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