Synthesis and characterization of a polyacetylene derivative: Poly(N-methylpropargylamine)

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The polymerization of N-methylpropargylamine was carried out by var-ious transition metal catalysts. The polymerizations of N-methylpropar-gylamine using the Pd, Pt, and Ru chlorides proceeded well in mild homogeneous manner to give the corresponding polymers in moderate yields. The chemical structure of poly(N-methylpropargylamine) was characterized by such instrumental methods as NMR (H-1-, C-13-), IR, UV-visible spectroscopies, and elemental analysis to have the designed conjugated polymer structure. The photoluminescence peak of poly(N-methylpropargylamine) was observed at 444nm, which is corresponded to the photon energy of 2.79eV. The electrochemical properties were also measured and discussed.
Publisher
TAYLOR & FRANCIS LTD
Issue Date
2018-06
Language
English
Article Type
Article; Proceedings Paper
Keywords

TRANSITION-METAL CATALYSTS; PLASMA-POLYMERIZED PROPARGYLAMINE; METATHESIS POLYMERIZATION; CYCLOPOLYMERIZATION; NANOCOMPOSITE; POLYANILINE; TRANSISTORS; ACETYLENES; GRAPHENE

Citation

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.662, no.1, pp.32 - 37

ISSN
1542-1406
DOI
10.1080/15421406.2018.1466238
URI
http://hdl.handle.net/10203/243701
Appears in Collection
CH-Journal Papers(저널논문)
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