DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhang, Jianbo | ko |
dc.contributor.author | Park, Sehoon | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2017-11-21T04:06:57Z | - |
dc.date.available | 2017-11-21T04:06:57Z | - |
dc.date.created | 2017-11-20 | - |
dc.date.created | 2017-11-20 | - |
dc.date.issued | 2017-10 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.44, pp.13757 - 13761 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/227209 | - |
dc.description.abstract | Described herein is the selective reduction of sugars with hydrosilanes catalyzed by using Piers' borane [(C6F5)(2)BH] generated in situ. The hydrosilylative C-O bond cleavage of silyl-protected mono-and disaccharides in the presence of a (C6F5)(2)BH catalyst, generated in situ from (C6F5)(2)BOH, takes place with excellent chemo- and regioselectivities to provide a range of polyols. A study of the substituent effects of sugars on the catalytic activity and selectivity revealed that the steric environment around the anomeric carbon (C1) is crucial. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | BIS(PENTAFLUOROPHENYL)BORINIC ACID | - |
dc.subject | B(C6F5)(3)-CATALYZED HYDROSILATION | - |
dc.subject | HYDROSILYLATION CATALYSTS | - |
dc.subject | ALKENE HYDROSILYLATION | - |
dc.subject | TERTIARY SILANES | - |
dc.subject | ALKYL ETHERS | - |
dc.subject | H-H | - |
dc.subject | REDUCTION | - |
dc.subject | HYDROGENATION | - |
dc.subject | DEOXYGENATION | - |
dc.title | Selective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers' Borane Generated In Situ | - |
dc.type | Article | - |
dc.identifier.wosid | 000413314800038 | - |
dc.identifier.scopusid | 2-s2.0-85030479396 | - |
dc.type.rims | ART | - |
dc.citation.volume | 56 | - |
dc.citation.issue | 44 | - |
dc.citation.beginningpage | 13757 | - |
dc.citation.endingpage | 13761 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201708109 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Zhang, Jianbo | - |
dc.contributor.nonIdAuthor | Park, Sehoon | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | bond cleavage | - |
dc.subject.keywordAuthor | chemoselectivity | - |
dc.subject.keywordAuthor | hydrosilylative reduction | - |
dc.subject.keywordAuthor | Piers&apos | - |
dc.subject.keywordAuthor | borane | - |
dc.subject.keywordAuthor | sugars | - |
dc.subject.keywordPlus | BIS(PENTAFLUOROPHENYL)BORINIC ACID | - |
dc.subject.keywordPlus | B(C6F5)(3)-CATALYZED HYDROSILATION | - |
dc.subject.keywordPlus | HYDROSILYLATION CATALYSTS | - |
dc.subject.keywordPlus | ALKENE HYDROSILYLATION | - |
dc.subject.keywordPlus | TERTIARY SILANES | - |
dc.subject.keywordPlus | ALKYL ETHERS | - |
dc.subject.keywordPlus | H-H | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | HYDROGENATION | - |
dc.subject.keywordPlus | DEOXYGENATION | - |
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