Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect
Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)](2+) complex via an anion effect. Our crystallo-graphic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)(2) produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)(2).
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2017-10
- Language
- English
- Article Type
- Article
- Keywords
CRYSTAL-STRUCTURE; CYCLAM LIGANDS; COORDINATING SOLVENTS; NICKEL(II) COMPLEXES; OXOIRON(IV) COMPLEX; ELECTRON-TRANSFER; AMINE COMPLEXES; PERCHLORATE; REACTIVITY; 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE
- Citation
DALTON TRANSACTIONS, v.46, no.39, pp.13166 - 13170
- ISSN
- 1477-9226
- Appears in Collection
- CH-Journal Papers(저널논문)
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