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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Synthesis of an ionic polyacetylene derivative via phosphorus oxychloride-activated polymerization of 2-ethynylpyridine

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dc.contributor.authorGal, Yeong-Soonko
dc.contributor.authorJin, Sung-Hoko
dc.contributor.authorLee, Sujiko
dc.contributor.authorPark, Jong Wookko
dc.contributor.authorLim, Kwon Taekko
dc.contributor.authorKim, Sang Youlko
dc.date.accessioned2017-06-16T02:53:38Z-
dc.date.available2017-06-16T02:53:38Z-
dc.date.created2017-06-02-
dc.date.created2017-06-02-
dc.date.created2017-06-02-
dc.date.issued2017-
dc.identifier.citationMOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.644, no.1, pp.227 - 233-
dc.identifier.issn1542-1406-
dc.identifier.urihttp://hdl.handle.net/10203/223968-
dc.description.abstractA new ionic polyacetylene was synthesized via the non-catalyst polymerization of 2-ethynylpyridine using phosphorus oxychloride. The polymerization proceeded well in homogeneous manner to give a moderate yield of polymer (74%). The resulting polymer was completely soluble in polar organic solvents including water. The photoluminescence spectrum showed the two maximum peaks of 471nm and 489nm corresponding to the photon energy of 2.64eV and 2.54eV, respectively. The oxidation and reduction onset potentials of polymer were observed at 970 and -130mV, respectively.-
dc.languageEnglish-
dc.publisherTAYLOR & FRANCIS LTD-
dc.titleSynthesis of an ionic polyacetylene derivative via phosphorus oxychloride-activated polymerization of 2-ethynylpyridine-
dc.typeArticle-
dc.identifier.wosid000400334900031-
dc.identifier.scopusid2-s2.0-85018347321-
dc.type.rimsART-
dc.citation.volume644-
dc.citation.issue1-
dc.citation.beginningpage227-
dc.citation.endingpage233-
dc.citation.publicationnameMOLECULAR CRYSTALS AND LIQUID CRYSTALS-
dc.identifier.doi10.1080/15421406.2016.1277493-
dc.contributor.localauthorKim, Sang Youl-
dc.contributor.nonIdAuthorGal, Yeong-Soon-
dc.contributor.nonIdAuthorJin, Sung-Ho-
dc.contributor.nonIdAuthorLee, Suji-
dc.contributor.nonIdAuthorPark, Jong Wook-
dc.contributor.nonIdAuthorLim, Kwon Taek-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorPolyacetylene-
dc.subject.keywordAuthorphosphorus oxychloride-
dc.subject.keywordAuthor2-ethynylpyridine-
dc.subject.keywordAuthornon-catalyst polymerization-
dc.subject.keywordAuthorcyclic voltammogram-
dc.subject.keywordPlusNONLINEAR-OPTICAL PROPERTIES-
dc.subject.keywordPlusUNCATALYZED POLYMERIZATION-
dc.subject.keywordPlusCONJUGATED POLYMER-
dc.subject.keywordPlusMETATHESIS POLYMERIZATION-
dc.subject.keywordPlusSIDE-CHAINS-
dc.subject.keywordPlusCYCLOPOLYMERIZATION-
dc.subject.keywordPlusMORPHOLOGY-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusBROMIDE)-
dc.subject.keywordPlusFILMS-
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