sigma-Complexation as a strategy for designing copper-based light emitters

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Strongly emissive cuprous complexes containing a stable sigma-SiH-Cu motif were prepared. These complexes serve as a proof of principle that sigma-complexation can be utilized as a design principle for engineering responsive light emitting materials. Their excited state lifetimes were found to be long (similar to 20 mu s) with high quantum yields (phi = 0.40-0.59).
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2017-02
Language
English
Article Type
Article
Keywords

DELAYED FLUORESCENCE; EMITTING-DIODES; COORDINATION; LIGAND; CU(I); PHOSPHORESCENCE; LUMINESCENCE; REACTIVITY; PROTEINS

Citation

CHEMICAL COMMUNICATIONS, v.53, no.19, pp.2858 - 2861

ISSN
1359-7345
DOI
10.1039/c6cc10139a
URI
http://hdl.handle.net/10203/223028
Appears in Collection
CH-Journal Papers(저널논문)
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