Rh(0)/Rh(III) core-shell nanoparticles as heterogeneous catalysts for cyclic carbonate synthesis

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Rh(0)/Rh(III) core-shell nanoparticles were prepared by surface oxidation of Rh nanoparticles with N-bromosuccinimide. They were employed as heterogeneous catalysts for cyclic carbonate synthesis from propylene oxide and CO2, and exhibited high activity and excellent recyclability due to Lewis acidic Rh(III) species on the shells.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2017-01
Language
English
Article Type
Article
Keywords

RHODIUM NANOPARTICLES; PALLADIUM; HYDROGENATION; NANOCATALYSTS; NANOSCIENCE; SELECTIVITY

Citation

CHEMICAL COMMUNICATIONS, v.53, no.2, pp.384 - 387

ISSN
1359-7345
DOI
10.1039/c6cc08318h
URI
http://hdl.handle.net/10203/220958
Appears in Collection
CH-Journal Papers(저널논문)
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