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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

[60]fullerene as a versatile four-electron donor ligand

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dc.contributor.authorSong, Hyunjoonko
dc.contributor.authorLee, Kko
dc.contributor.authorChoi, MGko
dc.contributor.authorPark, Joon Taikko
dc.date.accessioned2010-12-24T02:29:49Z-
dc.date.available2010-12-24T02:29:49Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2002-04-
dc.identifier.citationORGANOMETALLICS, v.21, no.9, pp.1756 - 1758-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10203/21222-
dc.description.abstractA new 1,2-sigma-type C-60 compound, OS3(CO)(7)(CNR)(mu(3)-CNR)(PPh3)(mu(3)-eta(1):eta(1):eta(2)-C-60) (2; R = CH2Ph), is formed from Os-3(CO)(8)(CNR)(mu(3)-CNR)(mu(3)-eta(1):eta(2):eta(1)-C-60) (1) upon substitution of CO with PPh3 on a triosmium cluster framework. Compounds 1 and 2 are reversibly interconvertible. Further reaction of 2 with PPh3 results in a pi-type C-60 complex, Os-3(CO)(6)(CNR)(mu(3)-CNCH2C6H4)(PPh3)(mu-PPh2)(mu-eta(2):eta(2)-C-60) (3), with an Os-Os bond cleavage.-
dc.description.sponsorshipThis work was supported by the National Research Laboratory (NRL) Program of the Korean Ministry of Science & Technology (MOST) and the Korea Science Engineering Foundation (Project No.1999-1-122-001-5).en
dc.languageEnglish-
dc.language.isoen_USen
dc.publisherAMER CHEMICAL SOC-
dc.subjectTRIOSMIUM CLUSTER COMPLEXES-
dc.subjectSTRUCTURAL CHARACTERIZATION-
dc.subjectC-60-
dc.subjectMU(3)-ETA(2),ETA(2),ETA(2)-C-60-
dc.subjectPENTARUTHENIUM-
dc.subjectDERIVATIVES-
dc.title[60]fullerene as a versatile four-electron donor ligand-
dc.typeArticle-
dc.identifier.wosid000175369600004-
dc.identifier.scopusid2-s2.0-0000628319-
dc.type.rimsART-
dc.citation.volume21-
dc.citation.issue9-
dc.citation.beginningpage1756-
dc.citation.endingpage1758-
dc.citation.publicationnameORGANOMETALLICS-
dc.embargo.liftdate9999-12-31-
dc.embargo.terms9999-12-31-
dc.contributor.localauthorSong, Hyunjoon-
dc.contributor.localauthorPark, Joon Taik-
dc.contributor.nonIdAuthorLee, K-
dc.contributor.nonIdAuthorChoi, MG-
dc.type.journalArticleArticle-
dc.subject.keywordPlusTRIOSMIUM CLUSTER COMPLEXES-
dc.subject.keywordPlusSTRUCTURAL CHARACTERIZATION-
dc.subject.keywordPlusC-60-
dc.subject.keywordPlusMU(3)-ETA(2),ETA(2),ETA(2)-C-60-
dc.subject.keywordPlusPENTARUTHENIUM-
dc.subject.keywordPlusDERIVATIVES-
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