DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Ansoo | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.date.accessioned | 2016-07-06T04:22:21Z | - |
dc.date.available | 2016-07-06T04:22:21Z | - |
dc.date.created | 2016-06-08 | - |
dc.date.created | 2016-06-08 | - |
dc.date.created | 2016-06-08 | - |
dc.date.issued | 2016-05 | - |
dc.identifier.citation | JOURNAL OF ORGANIC CHEMISTRY, v.81, no.9, pp.3520 - 3527 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10203/209514 | - |
dc.description.abstract | A complementary solution for Rh-catalyzed enantioselective 1,2- and 1,4-arylation with two structurally related chiral ligands is reported. A chiral bicyclic bridgehead phosphoramidite (briphos) ligand.derived from 1-aminoindane was efficient for the 1,2-arylation of N-sulfonyl imines, while that derived from 1,2,3,4-tetrahydro-1-naphthylamine was efficient for 1,4-arylation of alpha,beta-unsaturated cyclic ketones. For alpha,beta-unsaturated N-tosyl ketimines, the briphos derived from 1-aminoindane was found to selectively provide gamma,gamma-diaryl N-tosyl enamines with high yields and stereoselectivities | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Chiral Bicyclic Bridgehead Phosphoramidite (Briphos) Ligands for Asymmetric Rhodium-Catalyzed 1,2-and 1,4-Addition | - |
dc.type | Article | - |
dc.identifier.wosid | 000375890100006 | - |
dc.identifier.scopusid | 2-s2.0-84968764824 | - |
dc.type.rims | ART | - |
dc.citation.volume | 81 | - |
dc.citation.issue | 9 | - |
dc.citation.beginningpage | 3520 | - |
dc.citation.endingpage | 3527 | - |
dc.citation.publicationname | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.joc.6b00033 | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | PHOSPHINE-OLEFIN LIGANDS | - |
dc.subject.keywordPlus | BIS-SULFOXIDE LIGAND | - |
dc.subject.keywordPlus | ARYLBORONIC ACIDS | - |
dc.subject.keywordPlus | CONJUGATE ADDITION | - |
dc.subject.keywordPlus | DIPYRIDYLPHOSPHINE LIGANDS | - |
dc.subject.keywordPlus | REDUCTIVE ELIMINATION | - |
dc.subject.keywordPlus | N-TOSYLARYLIMINES | - |
dc.subject.keywordPlus | CARBON-CARBON | - |
dc.subject.keywordPlus | DIENE LIGANDS | - |
dc.subject.keywordPlus | BORONIC ACIDS | - |
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