Palladium-Catalyzed Divergent Arylation with Triazolopyridines: One-Pot Synthesis of 6-Aryl-2-alpha-styrylpyridines

Cited 10 time in webofscience Cited 0 time in scopus
  • Hit : 268
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorMoon, Youngtaekko
dc.contributor.authorKwon, Soonhyungko
dc.contributor.authorKang, Dahyeko
dc.contributor.authorIm, Hongguko
dc.contributor.authorHong, Sungwooko
dc.date.accessioned2016-07-04T01:57:29Z-
dc.date.available2016-07-04T01:57:29Z-
dc.date.created2016-04-27-
dc.date.created2016-04-27-
dc.date.issued2016-03-
dc.identifier.citationADVANCED SYNTHESIS & CATALYSIS, v.358, no.6, pp.958 - 964-
dc.identifier.issn1615-4150-
dc.identifier.urihttp://hdl.handle.net/10203/208774-
dc.description.abstractWe have developed a new strategy for palladium-catalyzed arylation reactions with triazolopyridines, wherein two different chemical transformations (C-3 vs. C-7) are observed by differentiating the substrates using different bases. The reactive palladium carbenoids were directly generated from triazolopyridines and underwent denitrogenative arylations with aryl bromides. Intriguingly, when potassium carbonate was replaced with potassium tert-butoxide, direct C-H arylation occurred at the most acidic position (C-7). Moreover, two different catalytic arylation events were successfully performed in a one-pot sequence, providing a convenient access to 6-aryl-2-alpha-styrylpyridines-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectRHODIUM(II) AZAVINYL CARBENES-
dc.subjectCROSS-COUPLING REACTIONS-
dc.subjectH BOND ACTIVATION-
dc.subjectARYLBORONIC ACIDS-
dc.subjectSULFONYL AZIDE-
dc.subjectARYL-
dc.subjectREACTIVITY-
dc.subjectTRIAZOLES-
dc.subjectALKYNES-
dc.subjectFUNCTIONALIZATION-
dc.titlePalladium-Catalyzed Divergent Arylation with Triazolopyridines: One-Pot Synthesis of 6-Aryl-2-alpha-styrylpyridines-
dc.typeArticle-
dc.identifier.wosid000373159200013-
dc.identifier.scopusid2-s2.0-84956555436-
dc.type.rimsART-
dc.citation.volume358-
dc.citation.issue6-
dc.citation.beginningpage958-
dc.citation.endingpage964-
dc.citation.publicationnameADVANCED SYNTHESIS & CATALYSIS-
dc.identifier.doi10.1002/adsc.201500967-
dc.contributor.localauthorHong, Sungwoo-
dc.contributor.nonIdAuthorIm, Honggu-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorarylation-
dc.subject.keywordAuthorcarbenes-
dc.subject.keywordAuthorone-pot reaction-
dc.subject.keywordAuthorpalladium-
dc.subject.keywordAuthortriazolopyridines-
dc.subject.keywordPlusRHODIUM(II) AZAVINYL CARBENES-
dc.subject.keywordPlusCROSS-COUPLING REACTIONS-
dc.subject.keywordPlusH BOND ACTIVATION-
dc.subject.keywordPlusARYLBORONIC ACIDS-
dc.subject.keywordPlusSULFONYL AZIDE-
dc.subject.keywordPlusARYL-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusTRIAZOLES-
dc.subject.keywordPlusALKYNES-
dc.subject.keywordPlusFUNCTIONALIZATION-
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 10 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0