DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Young-Choon | ko |
dc.contributor.author | An, Heesun | ko |
dc.contributor.author | Lee, Yoon Sup | ko |
dc.contributor.author | Baeck, Kyung Koo | ko |
dc.date.accessioned | 2016-06-28T02:02:02Z | - |
dc.date.available | 2016-06-28T02:02:02Z | - |
dc.date.created | 2016-03-21 | - |
dc.date.created | 2016-03-21 | - |
dc.date.issued | 2016-02 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY A, v.120, no.6, pp.932 - 938 | - |
dc.identifier.issn | 1089-5639 | - |
dc.identifier.uri | http://hdl.handle.net/10203/207979 | - |
dc.description.abstract | Fano resonance in the predissociation of the S-1 state of diazirine was studied by applying a time-dependent wave packet propagation method, and dynamic symmetry breaking (DSB) around the stationary structure of S-1 was disclosed in a detailed analysis of this theoretical result. The DSB was found to originate in coupling between the asymmetric C-N-2 stretching and CH2 wagging modes, suggesting that there is a slight time gap between ring opening and the concurrent dragging of two H atoms of the CH2 moiety. Although the depth of the double well due to DSB is just 0.011 eV, its presence noticeably affects the early time dynamics and observed spectrum. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | SCHRODINGER-EQUATION | - |
dc.subject | ANALYTIC GRADIENT | - |
dc.subject | CARBENE FORMATION | - |
dc.subject | BRANCHING RATIO | - |
dc.subject | EXCITED-STATE | - |
dc.subject | ORBITAL SPACE | - |
dc.subject | MC-SCF | - |
dc.subject | TIME | - |
dc.subject | PHOTODISSOCIATION | - |
dc.subject | PREDISSOCIATION | - |
dc.title | Dynamic Symmetry Breaking Hidden in Fano Resonance of a Molecule: S-1 State of Diazirine Using Quantum Wave Packet Propagation | - |
dc.type | Article | - |
dc.identifier.wosid | 000370678600010 | - |
dc.identifier.scopusid | 2-s2.0-84959036281 | - |
dc.type.rims | ART | - |
dc.citation.volume | 120 | - |
dc.citation.issue | 6 | - |
dc.citation.beginningpage | 932 | - |
dc.citation.endingpage | 938 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.identifier.doi | 10.1021/acs.jpca.5b11052 | - |
dc.contributor.localauthor | Lee, Yoon Sup | - |
dc.contributor.nonIdAuthor | An, Heesun | - |
dc.contributor.nonIdAuthor | Baeck, Kyung Koo | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | SCHRODINGER-EQUATION | - |
dc.subject.keywordPlus | ANALYTIC GRADIENT | - |
dc.subject.keywordPlus | CARBENE FORMATION | - |
dc.subject.keywordPlus | BRANCHING RATIO | - |
dc.subject.keywordPlus | EXCITED-STATE | - |
dc.subject.keywordPlus | ORBITAL SPACE | - |
dc.subject.keywordPlus | MC-SCF | - |
dc.subject.keywordPlus | TIME | - |
dc.subject.keywordPlus | PHOTODISSOCIATION | - |
dc.subject.keywordPlus | PREDISSOCIATION | - |
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