Comparative Catalytic Activity of Group 9 [Cp*M-III] Complexes: Cobalt-Catalyzed C-H Amidation of Arenes with Dioxazolones as Amidating Reagents

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A procedure for the [Cp*Co-III]-catalyzed direct C-H amidation of arenes with dioxazolone has been developed. This reaction proceeds under straightforward and mild conditions with a broad range of substrates, including anilides. A comparative study on the catalytic activity of Group 9 [{Cp*MCl2}(2)] complexes revealed the unique efficiency of the cobalt catalyst.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2015-11
Language
English
Article Type
Article
Keywords

NITRENE TRANSFER-REACTIONS; N BOND FORMATION; NITROGEN-SOURCE; ROOM-TEMPERATURE; AMINO SOURCES; ACTIVATION; AMINATION; FUNCTIONALIZATION; AZIDES; MILD

Citation

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.54, no.47, pp.14103 - 14107

ISSN
1433-7851
DOI
10.1002/anie.201505820
URI
http://hdl.handle.net/10203/207849
Appears in Collection
CH-Journal Papers(저널논문)
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