Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive

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dc.contributor.authorKang, Kyungjunko
dc.contributor.authorKim, Jaewookko
dc.contributor.authorLee, Ansooko
dc.contributor.authorKim, Woo Younko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2016-05-16T08:44:50Z-
dc.date.available2016-05-16T08:44:50Z-
dc.date.created2016-02-21-
dc.date.created2016-02-21-
dc.date.issued2016-02-
dc.identifier.citationORGANIC LETTERS, v.18, no.3, pp.616 - 619-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/207426-
dc.description.abstractA mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite (briphos) ligand together with Pd(dba)(2) is a highly efficient catalyst, and an acid additive involved in the rate-determining step promotes the catalytic cycle. The coupling reaction of allylic alcohols with N-heterocycles including imidazoles, benzimidazoles, and triazole proceeds under mild reaction conditions with high yields using Pd/briphos and pentafluorophenol.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectAQUEOUS-MEDIA-
dc.subjectBOND-CLEAVAGE-
dc.subjectAMINO-ACID-
dc.subjectALLYLATION-
dc.subjectAMINATION-
dc.subjectSUBSTITUTION-
dc.subjectACTIVATION-
dc.subjectWATER-
dc.subjectNUCLEOPHILES-
dc.subjectCOMPLEXES-
dc.titlePalladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive-
dc.typeArticle-
dc.identifier.wosid000369771800069-
dc.identifier.scopusid2-s2.0-84957599473-
dc.type.rimsART-
dc.citation.volume18-
dc.citation.issue3-
dc.citation.beginningpage616-
dc.citation.endingpage619-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.6b00001-
dc.contributor.localauthorKim, Woo Youn-
dc.contributor.localauthorKim, Hyunwoo-
dc.type.journalArticleArticle-
dc.subject.keywordPlusAQUEOUS-MEDIA-
dc.subject.keywordPlusBOND-CLEAVAGE-
dc.subject.keywordPlusAMINO-ACID-
dc.subject.keywordPlusALLYLATION-
dc.subject.keywordPlusAMINATION-
dc.subject.keywordPlusSUBSTITUTION-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusWATER-
dc.subject.keywordPlusNUCLEOPHILES-
dc.subject.keywordPlusCOMPLEXES-
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