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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Rhodium-Catalyzed Asymmetric 1,4-Addition of alpha,beta-Unsaturated Imino Esters Using Chiral Bicyclic Bridgehead Phosphoramidite Ligands

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dc.contributor.authorLee, Ansooko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2016-04-20T06:28:37Z-
dc.date.available2016-04-20T06:28:37Z-
dc.date.created2015-10-13-
dc.date.created2015-10-13-
dc.date.created2015-10-13-
dc.date.issued2015-09-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.35, pp.11250 - 11253-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/205366-
dc.description.abstractA chiral bicyclic bridgehead phosphoramidite (briphos) prepared from 1-aminoindane is a highly efficient and selective ligand for rhodium(I)-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated N,N-dimethyl-sulfamoyl imino esters at ambient temperature. This transformation provides a new class of chiral (Z)-gamma,gamma-diaryl-alpha,beta-dehydroamino esters with excellent yield and enantioselectivity.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleRhodium-Catalyzed Asymmetric 1,4-Addition of alpha,beta-Unsaturated Imino Esters Using Chiral Bicyclic Bridgehead Phosphoramidite Ligands-
dc.typeArticle-
dc.identifier.wosid000361251600012-
dc.identifier.scopusid2-s2.0-84941219346-
dc.type.rimsART-
dc.citation.volume137-
dc.citation.issue35-
dc.citation.beginningpage11250-
dc.citation.endingpage11253-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/jacs.5b07034-
dc.contributor.localauthorKim, Hyunwoo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusPHOSPHINE-OLEFIN LIGANDS-
dc.subject.keywordPlusBIS-SULFOXIDE LIGAND-
dc.subject.keywordPlusARYLBORONIC ACIDS-
dc.subject.keywordPlusCONJUGATE ADDITION-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusDIENE LIGANDS-
dc.subject.keywordPlusBORONIC ACIDS-
dc.subject.keywordPlusALKENYLBORONIC ACIDS-
dc.subject.keywordPlusN-TOSYLARYLIMINES-
dc.subject.keywordPlusALPHA-KETOESTERS-
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