A non-classical hydrogen bond in the molybdenum arene complex [eta(6)-C6H5C6H3(Ph)OH]Mo(PMe3)(3): evidence that hydrogen bonding facilitates oxidative addition of the O-H bond

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Mo(PMe3)(6) reacts with 2,6-Ph2C6H3OH to give the eta(6)-arene complex [eta(6)-C6H5C6H3(Ph)OH]Mo(PMe3)(3) which exhibits a non-classical Mo...H-OAr hydrogen bond; DFT calculations indicate that the hydrogen bonding interaction facilitates oxidative addition of the O-H bond to give [eta(6),eta(1)- C6H5C6H3(Ph)O]Mo(PMe3)(2)H.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2002-11
Language
English
Article Type
Article
Keywords

TRANSITION-METAL CENTERS; TUNGSTEN

Citation

CHEMICAL COMMUNICATIONS, no.22, pp.2644 - 2645

ISSN
1359-7345
DOI
10.1039/b208678f
URI
http://hdl.handle.net/10203/203369
Appears in Collection
CH-Journal Papers(저널논문)
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