A four-coordinate thionitrosyl complex of vanadium

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Addition of elemental sulfur to the vanadium nitride [(nacnac)V N(OAr)] forms the first thionitrosyl complex of vanadium, [(nacnac)V(NS)(OAr)]. Single crystal X-Ray diffraction studies and DFT calculations reveal an almost linear thionitrosyl ligand resulting from an extended pi-resonance across the VNS moiety.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2013
Language
English
Article Type
Article
Keywords

ELECTRONIC-STRUCTURES; CRYSTAL-STRUCTURE; OSMIUM(VI) NITRIDES; NITROSYL COMPLEXES; AZIDE ION; REACTIVITY; CHEMISTRY; RHENIUM

Citation

CHEMICAL COMMUNICATIONS, v.49, no.27, pp.2768 - 2770

ISSN
1359-7345
DOI
10.1039/c3cc38799b
URI
http://hdl.handle.net/10203/203298
Appears in Collection
CH-Journal Papers(저널논문)
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