A computational study of the mechanism of the [(salen)Cr + DMAP]-catalyzed formation of cyclic carbonates from CO2 and epoxide

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Epoxide and CO2 coupling reactions catalyzed by (salen)(CrCl)-Cl-III have been modeled computationally to contrast a monometallic vs. a bimetallic mechanism. A low-energy CO2 insertion step into the metal-alkoxide bond was located.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2014
Language
English
Article Type
Article
Keywords

CARBON-DIOXIDE; SALEN COMPLEXES; CYCLIC CARBONATES; ASYMMETRIC CATALYSIS; CYCLOHEXENE OXIDE; PROPYLENE-OXIDE; EPOXIDES; CO2; COPOLYMERIZATION; POLYCARBONATES

Citation

CHEMICAL COMMUNICATIONS, v.50, no.20, pp.2676 - 2678

ISSN
1359-7345
DOI
10.1039/c3cc48769e
URI
http://hdl.handle.net/10203/203294
Appears in Collection
CH-Journal Papers(저널논문)
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