A computational study of the mechanism of the [(salen)Cr + DMAP]-catalyzed formation of cyclic carbonates from CO2 and epoxide
Epoxide and CO2 coupling reactions catalyzed by (salen)(CrCl)-Cl-III have been modeled computationally to contrast a monometallic vs. a bimetallic mechanism. A low-energy CO2 insertion step into the metal-alkoxide bond was located.
- Publisher
- ROYAL SOC CHEMISTRY
- Issue Date
- 2014
- Language
- English
- Article Type
- Article
- Keywords
CARBON-DIOXIDE; SALEN COMPLEXES; CYCLIC CARBONATES; ASYMMETRIC CATALYSIS; CYCLOHEXENE OXIDE; PROPYLENE-OXIDE; EPOXIDES; CO2; COPOLYMERIZATION; POLYCARBONATES
- Citation
CHEMICAL COMMUNICATIONS, v.50, no.20, pp.2676 - 2678
- ISSN
- 1359-7345
- Appears in Collection
- CH-Journal Papers(저널논문)
- Files in This Item
- There are no files associated with this item.
This item is cited by other documents in WoS
| ⊙ Detail Information in WoSⓡ | Click to see |  |
| ⊙ Cited 60 items in WoS | Click to see citing articles in |  |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.