Synthesis of Phosphoramidates: A Facile Approach Based on the C-N Bond Formation via Ir-Catalyzed Direct C-H Amidation

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A new synthetic route to phosphoramidates by intermolecular C-H amidation is presented. Substrates with assorted directing groups were activated by an iridium-based catalyst system and reacted with a number of phosphoryl azides, executing efficient phosphoramidate synthesis via C-N bond formations. (Chemical Equation Presented).
Publisher
AMER CHEMICAL SOC
Issue Date
2014-10
Language
English
Article Type
Article
Keywords

PHOSPHORYL AZIDES; ARYL AZIDES; CONVENIENT SYNTHESIS; 1,2-AMINO ALCOHOLS; MASS-SPECTROMETRY; FORMING REACTIONS; FLAME-RETARDANT; NITROGEN-SOURCE; ACTIVATION; AMINATION

Citation

ORGANIC LETTERS, v.16, no.20, pp.5466 - 5469

ISSN
1523-7060
DOI
10.1021/ol502722j
URI
http://hdl.handle.net/10203/199014
Appears in Collection
CH-Journal Papers(저널논문)
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