Cobalt(III)-Catalyzed C-H Amidation of Arenes using Acetoxycarbamates as Convenient Amino Sources under Mild Conditions

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The Co(III)-catalyzed direct C-H amidation of arenes has been developed using O-acylcarbamates as a convenient amino source. This reaction proceeded in high efficiency under external oxidant-free conditions with a broad range of arene substrates, including 6-arylpurines bearing sensitive functional groups, thus furnishing synthetically versatile arene N-carbamate products.
Publisher
AMER CHEMICAL SOC
Issue Date
2015-02
Language
English
Article Type
Article
Keywords

N BOND FORMATION; ROOM-TEMPERATURE; 6-ARYLPURINE NUCLEOSIDES; PROTECTED ARYLAMINES; CYTOSTATIC ACTIVITY; DIRECT AMINATION; SULFONYL AZIDES; ARYL AZIDES; ACTIVATION; FUNCTIONALIZATION

Citation

ACS CATALYSIS, v.5, no.2, pp.853 - 858

ISSN
2155-5435
DOI
10.1021/cs501860b
URI
http://hdl.handle.net/10203/195825
Appears in Collection
CH-Journal Papers(저널논문)
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