Radical Chlorination with Hypervalent Iodine(III) Generated by Ligand Exchange: Revisiting Palladium(II)-Catalyzed Directed C-H Chlorination

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A simple protocol to generate radical chlorine species by ligand exchange in hypervalent iodine(III) compounds is reported. Radical chlorine species, not electrophilic chlorine species, are required for Pd-catalyzed directed C-H chlorination and ammonium salts can be used as radical chlorine sources.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2015-02
Language
English
Article Type
Article
Keywords

POLYVALENT IODINE; REDUCTIVE ELIMINATION; AROMATIC-COMPOUNDS; CATALYTIC METHOD; REAGENTS; HALOGENATION; OXIDATION; CHEMISTRY; FUNCTIONALIZATION; SELECTIVITY

Citation

ASIAN JOURNAL OF ORGANIC CHEMISTRY, v.4, no.2, pp.137 - 140

ISSN
2193-5807
DOI
10.1002/ajoc.201402284
URI
http://hdl.handle.net/10203/195556
Appears in Collection
CH-Journal Papers(저널논문)
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