Reversibly tunable helix inversion in supramolecular gels trigged by Co2+

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dc.contributor.authorPark, So Hyeonko
dc.contributor.authorJung, Sung Hoko
dc.contributor.authorAhn, Junhoko
dc.contributor.authorLee, Ji Hako
dc.contributor.authorKwon, Ki-Youngko
dc.contributor.authorJeon, Jiwonko
dc.contributor.authorKim, Hyung-Junko
dc.contributor.authorJaworski, Justynko
dc.contributor.authorJung, Jong Hwako
dc.date.accessioned2015-04-06T05:53:38Z-
dc.date.available2015-04-06T05:53:38Z-
dc.date.created2014-12-09-
dc.date.created2014-12-09-
dc.date.issued2014-11-
dc.identifier.citationCHEMICAL COMMUNICATIONS, v.50, no.88, pp.13495 - 13498-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10203/194723-
dc.description.abstractTerpyridine-based ligands form octahedral complexes with Co2+ at Low cation concentrations to form helical assemblies which provide a supramolecular gel framework. Increasing the Co2+ concentration above 0.6 equiv. reveals a second, co-existing square pyramidal complex derived assembly, having a distinct helicity. While this geometry dominates at 1 equiv. of Co2+, we find this unique form of helical inversion to be fully reversible and controllable.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectCROSSOVER COBALT(II) COMPOUND-
dc.subjectDYNAMIC HELICITY INVERSION-
dc.subjectSPIN-CROSSOVER-
dc.subjectLIQUID-CRYSTALS-
dc.subjectZ-DNA-
dc.subjectCOMPLEX-
dc.subjectPOLYMERS-
dc.subjectSENSE-
dc.subjectSTABILIZATION-
dc.subjectTEMPERATURE-
dc.titleReversibly tunable helix inversion in supramolecular gels trigged by Co2+-
dc.typeArticle-
dc.identifier.wosid000343965300017-
dc.identifier.scopusid2-s2.0-84907967259-
dc.type.rimsART-
dc.citation.volume50-
dc.citation.issue88-
dc.citation.beginningpage13495-
dc.citation.endingpage13498-
dc.citation.publicationnameCHEMICAL COMMUNICATIONS-
dc.identifier.doi10.1039/c4cc05699j-
dc.contributor.localauthorKim, Hyung-Jun-
dc.contributor.nonIdAuthorPark, So Hyeon-
dc.contributor.nonIdAuthorJung, Sung Ho-
dc.contributor.nonIdAuthorAhn, Junho-
dc.contributor.nonIdAuthorLee, Ji Ha-
dc.contributor.nonIdAuthorKwon, Ki-Young-
dc.contributor.nonIdAuthorJaworski, Justyn-
dc.contributor.nonIdAuthorJung, Jong Hwa-
dc.type.journalArticleArticle-
dc.subject.keywordPlusCROSSOVER COBALT(II) COMPOUND-
dc.subject.keywordPlusDYNAMIC HELICITY INVERSION-
dc.subject.keywordPlusSPIN-CROSSOVER-
dc.subject.keywordPlusLIQUID-CRYSTALS-
dc.subject.keywordPlusZ-DNA-
dc.subject.keywordPlusCOMPLEX-
dc.subject.keywordPlusPOLYMERS-
dc.subject.keywordPlusSENSE-
dc.subject.keywordPlusSTABILIZATION-
dc.subject.keywordPlusTEMPERATURE-
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