A highly Lewis-acidic Pd(IV) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions

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The Pd(IV) species, known to be critical intermediates in homogeneous catalysis, were successfully generated on the surface of Pd nanocatalysts via oxidation with iodobenzene dichloride (PhICl2) or N-chlorosuccinimide (NCS). In particular, the Pd@SiO2 yolk-shell nanocatalyst activated by PhICl2 showed high reactivity and superior stability to the other Pd-based catalysts for hydroalkoxylation reactions even at 25 degrees C.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2014-12
Language
English
Article Type
Article
Keywords

YOLK-SHELL NANOCATALYSTS; CROSS-COUPLING REACTIONS; HETEROGENEOUS CATALYSIS; NANOPARTICLES; SELECTIVITY; SHAPE; NANOSCIENCE; REACTIVITY; STABILITY; CHEMISTRY

Citation

CHEMICAL COMMUNICATIONS, v.50, no.95, pp.14938 - 14941

ISSN
1359-7345
DOI
10.1039/c4cc05112b
URI
http://hdl.handle.net/10203/193886
Appears in Collection
CH-Journal Papers(저널논문)
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