Selenium- and Tellurium-Containing Fluorescent Molecular Probes for the Detection of Biologically Important Analytes

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CONSPECTUS: As scientists in recent decades have discovered, selenium is an important trace element in life. The element is now known to play an important role in biology as an enzymatic antioxidant. In this case, it sits at the active site and converts biological hydrogen peroxides to water. Mimicking this reaction, chemists have synthesized several organoselenium compounds that undergo redox transformations. As such, these types of compounds are important in the future of both medicinal and materials chemistry. One main challenge for organochalcogen chemists has been to synthesize molecular probes that are soluble in water where a selenium or tellurium center can best modify electronics of the molecule based on a chemical oxidation or reduction event.
Publisher
AMER CHEMICAL SOC
Issue Date
2014-10
Language
English
Article Type
Review
Keywords

LIVING CELLS; GLUTATHIONE-PEROXIDASE; ANTIOXIDANT ACTIVITY; OXIDATIVE STRESS; TURN-ON; DIARYL DISELENIDES; HYPOCHLORIC ACID; REDOX CYCLE; SE-BODIPY; ORGANOSELENIUM

Citation

ACCOUNTS OF CHEMICAL RESEARCH, v.47, no.10, pp.2985 - 2998

ISSN
0001-4842
DOI
10.1021/ar500187v
URI
http://hdl.handle.net/10203/193082
Appears in Collection
CH-Journal Papers(저널논문)
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