AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

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AgSbF6-controlled diastereodivergent hydroarylation reactions were developed. Unprecedented and remarkable switching of the E/Z-stereoselectivity could be obtained by adjusting the AgSbF6 loading.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2014-06
Language
English
Article Type
Article
Keywords

C-H ACTIVATION; BOND ACTIVATION; CATALYSIS; DERIVATIVES; ANNULATION; PYRIDINES; CLEAVAGE; KETONES; FUNCTIONALIZATION; RHODIUM(III)

Citation

CHEMICAL COMMUNICATIONS, v.50, no.59, pp.8028 - 8031

ISSN
1359-7345
DOI
10.1039/c4cc03602f
URI
http://hdl.handle.net/10203/189982
Appears in Collection
CH-Journal Papers(저널논문)
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