A Chiral meso-ABC-Corrolatochromium(V) Complex

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A chiral metallocorrole complex, oxo[5-(4-bromophenyl)-10- (pentafluorophenyl)-15-(2-thianaphthyl)corrolato]chromium(V)(7), was prepared and serves as the first example of an ABC-metallocorrole; meso substituents are of different electron-withdrawing capacity. An adaptation of a multistep protocol (D. T. Gryko) was made, followed by an aerobic oxidation using Cr(CO)(6) (Z. Gross). The X-ray crystal structure reveals the two enantiomers of 7. Electron paramagnetic resonance spectroscopy (g(iso) = 1.99) and cyclic voltammetry of 7 provide comparative data to that of the A(3)[tris(pfp) cCr(V)O] complex.
Publisher
AMER CHEMICAL SOC
Issue Date
2009-06
Language
English
Article Type
Article
Keywords

CHROMIUM CORROLES; EFFICIENT SYNTHESIS; DIPYRROMETHANES; PORPHYRIN; FLUORESCENCE; DIPYRRINS; OXIDATION; MANGANESE; BEARING

Citation

INORGANIC CHEMISTRY, v.48, no.11, pp.4634 - 4636

ISSN
0020-1669
DOI
10.1021/ic900393v
URI
http://hdl.handle.net/10203/18631
Appears in Collection
CH-Journal Papers(저널논문)
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