Synthesis of hydrothermally stable MCM-41 by the seed crystallization and its application as a catalyst support for hydrodesulfurization

Cited 30 time in webofscience Cited 0 time in scopus
  • Hit : 682
  • Download : 314
MCM-41 is one of the weak hydrothermally stable members in M41s mesoporous silica family. Therefore, in the present work, an attention has been focused to improve its hydrothermal stability as well as to achieve more acidic sites on its surface structure, in order to make it a good candidate as a support for hydrodesulfurization (HDS) catalysts. Hydrothermally stable MCM-41 (MCM-41(HS)) has been successfully prepared by the seed crystallization method. The synthesized material was analyzed by the powder X-ray diffraction (XRD), nitrogen adsorption-desorption, ammonia-temperature programmed desorption (NH3-TPD), chemisorption of carbon monoxide (CO chemisorption), elemental analysis (EA) and solid NMR techniques. The characterization results showed that the hydrothermal stability of MCM-41(HS) was significantly improved due to presence of highly crosslinked framework walls, while the mesopore system remained highly ordered. The synthesized MCM-41(HS) has been initially used here as a support to prepare Mo/MCM-41(HS) catalyst for HDS application. The increased zeolitic phase in the wall of mesostructure is believed to increase the HDS activity of MCM-41(HS) supported Mo catalyst in contrast with conventional Al-MCM-41 supported Mo catalyst. (c) 2012 Elsevier Ltd. All rights reserved.
Publisher
ELSEVIER SCI LTD
Issue Date
2013-04
Language
English
Article Type
Article
Keywords

ALUMINOSILICATE MESOSTRUCTURES; MESOPOROUS ALUMINOSILICATES; ZEOLITE; STABILITY; AL-MCM-41; ALUMINA

Citation

FUEL, v.106, pp.787 - 792

ISSN
0016-2361
DOI
10.1016/j.fuel.2012.11.031
URI
http://hdl.handle.net/10203/173780
Appears in Collection
CBE-Journal Papers(저널논문)
Files in This Item
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 30 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0