Water in concrete has an effect on properties of concrete very much, such as shrinkage, creep, fire resistance, durability, freezing and thawing resistance. Therefore predicting the moisture distribution in concrete is very important. And since the diffusion process of water in concrete is strongly dependent on the temperature and pore humidity, the process is highly nonlinear phenomena. In this study, a finite element program which was capable of simulating the moisture distribution in concrete was developed, and differential drying shrinkage due to the water diffusion process was measured at the different positions of concrete. This F.E.M. program is shown that the analytical results of this study are in good agreement with experimental data. Shrinkage strain caused by moisture distribution was increased with the decrease of pore relative humidity.